Destabilized 2-Norbornyl Cations

✍ Scribed by Prof. Dr. Wolfgang Kirmse; Dipl.-Chem. Uwe Mrotzeck; Dr. Rainer Siegfried

• Book ID: 101555932
• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: English
• Weight: 238 KB
• Volume: 24
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198500551

✦ Synopsis

no satisfactory explanation for the complete order of the ozonide anions at room temperature, which is in contrast with the comparable RbN02151. Intermolecular interactions between the ozonide ions (dimerization) can be ruled out on the grounds of the large intermolecular distances[31. Also still inexplicable are the marked differences in the stability of the compounds with 19-electron systems (NF2, SO 5, 0 7, S 7, CIOz) towards dimerization. Whichever of the conceivable criteria is analyzed for an explanation (repulsion of non-bonding electron pairs, differences in elec-tronegativityf6', charge of the monomer, state of aggregation) there are inconsistencies.