Desorption Studies of Hydrogen in Metal–Organic Frameworks
✍ Scribed by Barbara Panella; Katja Hönes; Ulrich Müller; Natalia Trukhan; Markus Schubert; Hermann Pütter; Michael Hirscher
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 324 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0044-8249
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## Abstract __Interaction between adsorbed hydrogen and the coordinatively unsaturated Mg^2+^ and Co^2+^ cationic centres in Mg‐MOF‐74 and Co‐MOF‐74, respectively, was studied by means of variable‐temperature infrared (VTIR) spectroscopy. Perturbation of the H~2~ molecule by the cationic adsorbing