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Desolvation of a Novel Microporous Hydrogen-Bonded Framework: Characterization by In Situ Single-Crystal and Powder X-ray Diffraction

✍ Scribed by Cameron J. Kepert; Dusan Hesek; Paul D. Beer; Matthew J. Rosseinsky

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 129 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19981204)37:22<3158::aid-anie3158>3.0.co;2-8

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✦ Synopsis

Despite significant structural rearrangement upon desolvation of a three-dimensional molecular framework of hexaaquacobalt cations and redox-active functionalized tetrathiafulvalene anions (see the picture; the area filled with water molecules is shown in gray), monocrystallinity and microporosity are retained. X-ray analyses show that a unique combination of hydrogen bonds and π⋅⋅⋅π interactions within the framework gives this material a structural flexibility not seen in zeolites or their analogues.

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