✦ LIBER ✦
Desilylation-triggered isomerization of a molecular capsule from an open-type to a collapsed-type isomer
✍ Scribed by Soichiro Watanabe; Kei Goto; Takayuki Kawashima; Renji Okazaki
- Book ID
- 104261358
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 247 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Desilylation of a triphenylsilyl-substituted molecular capsule lb(C) bearing a large inner space afforded la(C) with similar conformation, which underwent unidirectional and complete isomerization to a thermodynamically more favored isomer la(V) with a collapsed inner space by gentle heating in CDCiy