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Desilylation and conversion of trimethylsilylmethyl epoxides into ketones under the influence of a bulky base

✍ Scribed by Yuan Ma

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 213 KB
Volume: 13
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.10036

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✦ Synopsis

Abstract

Trimethylsilylmethyl epoxides were converted into ketones through a desilylation, epoxide ring‐opening, and rearrangement reaction under the influence of a bulky base in the presence of 18‐crown‐6. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:310–315, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10036

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