Designing Novel Organic—Inorganic Frameworks
✍ Scribed by Filipe A. Almeida Paz; Jacek Klinowski
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 18 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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The controlled synthesis of materials with very large pores is an ongoing challenge in the area of materials science. Research into large-pore materials is fueled by their use in catalysis, gas storage, and separation. [1] After intense development of inorganic frameworks in the early 1990s, [2] the
## Abstract Hydrothermal reactions of InCl~3~ with 1,3,5‐benzenetricarboxylic acid (H~3~BTC) or pyromellitic dianhydride produced [In~2~(BTC)~2~(H~2~O)~2~]~__n__~·2__n__H~2~O (1) and [In~2~(H~2~BTEC)~2~(OH)~2~]~__n__~·2__n__H~2~O (2), respectively (H~4~BTEC = 1,2,4,5‐benzenetetracarboxylic acid). T