Design, Synthesis, and Evaluation of Phe-Gly Mimetics: Heterocyclic Building Blocks for Pseudopeptides
β Scribed by Borg, Susanna; Vollinga, Roeland C.; Labarre, Maryse; Payza, Kemal; Terenius, Lars; Luthman, Kristina
- Book ID
- 127343220
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 529 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-2623
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The bisand tris(diazomethyl)phosphanes 5 and12 , obtained by electrophilic diasoalkane substitution of 4 or PC13 with lithiated 3 , are starting materials for complicated, heteroatom-substituted compounds. Thus, [3+2]-cycloadditions with the phosphaalkyne 9 and subsequent [1,5]-Tms shifts give rise