Design Optimization of 1,3-Diphospha-2,4-diboretane Diradicals
โ Scribed by Mark Seierstad; Christopher R. Kinsinger; Christopher J. Cramer
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 87 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The reactions of 2,3-dichloro-1,4-diphospha-1,3-butadiene, which is sterically protected with the 2,4,6-tri-t-butylphenyl group, with some nucleophiles, including alkyllithium reagents and lithium aluminum hydrides, afforded 1,2-diphosphinoacetylenes or 3-phosphino-1-phosphaallenes.
Cycloaromatization of a Non-Conjugated Polyenyne System: Synthesis of 5H-Benzo(d)fluoreno(3,2-b)pyrans via Diradicals Generated from 1-(2-(4-(2-Alkoxymethylphenyl)butan-1,3diynyl))phenylpentan-2,4-diyn-1-ols and Trapping Evidence for the 1,2-Didehydrobenzene Diradical. -Mild thermolysis of the tetr