Design of molecular switching and signaling based on proton transfer in 2-hydroxy Schiff bases: a computational study
β Scribed by Salem Abood Hameed, Saaban K. Alrouby, Rifaat Hilal
- Book ID
- 115469116
- Publisher
- Springer-Verlag
- Year
- 2012
- Tongue
- English
- Weight
- 653 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1610-2940
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The proton transfer equilibrium in series of Schi β bases derived from 5-nitrosalicylaldehyde and aliphatic amines was investigated by means of variable-temperature NMR spectra and the deuterium isotope e β ect on 13C NMR chemical shifts.
## Abstract The synthesis and characterisation of the heteroditopic ligand __N__,__N__β²βbis(3,5βdiβ__tert__βbutylsalicylidene)β5,6β(1,10βphenanthroline)diamine (DPSalH~2~) bearing a phenanthroline and a bis(salicylidene)diimine cavity are reported. This versatile ligand combines two of the most wid