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Design of kinetically coupled complex reaction systems

✍ Scribed by Concetta LaMarca; Cristian Libanati; Michael T. Klein

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
569 KB
Volume
45
Category
Article
ISSN
0009-2509

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✦ Synopsis

The reaction kinetics of multicomponent mixtures were explored through the mathematical and experimental analyses of binary pyrolysis systems.

The mathematical model was of parallel Rice-Herzfeld chains that were coupled through hydrogen transfer and termination elementary steps. Analytical rate expressions for the coupled systems led to criteria for the classification of binary interactions. This, in turn, provided rationale for "optimizing" the type of observed interaction. Experiments with the model compounds dibenzyl ether and phenethyl phenyl ether provided an experimental example of kinetically coupled Rice-Herzfeld pyrolysis chains.

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