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Design of and Mechanistic Studies on a Biomimetic Iron–Imidazole Catalyst System for Epoxidation of Olefins with Hydrogen Peroxide

✍ Scribed by Kristin Schröder; Stephan Enthaler; Bianca Bitterlich; Thomas Schulz; Anke Spannenberg; Man Kin Tse; Kathrin Junge; Matthias Beller


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
830 KB
Volume
15
Category
Article
ISSN
0947-6539

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Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl