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Design of a Novel Inherently Chiral Calix[4]arene for Chiral Molecular Recognition

✍ Scribed by Shirakawa, Seiji; Moriyama, Akihiro; Shimizu, Shoichi


Book ID
126125432
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
253 KB
Volume
9
Category
Article
ISSN
1523-7060

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## Abstract Chiral nitrogen‐containing calix[4]arene was easily synthesized by the reaction of 25,27‐di(2‐bromoethoxy)‐26,28‐dihydroxy‐5,11,17,23‐tetrakis(__t__‐butyl)calix[4]arene with __S__‐((βˆ’)‐1‐phenylethylamine in excellent yield, and showed good ability to recognize the enantiomers of mandeli