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Design in solid state chemistry based on phase homologies. Sb4Te3 and Sb8Te9 as new members of the series (Sb2Te3)m·(Sb2)n

✍ Scribed by Poudeu, Pierre F. P.; Kanatzidis, Mercouri G.


Book ID
120566443
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
326 KB
Volume
21
Category
Article
ISSN
1359-7345

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Design in Solid State Synthesis Based on
✍ Antje Mrotzek; Mercouri G. Kanatzidis 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 331 KB

Both the composition and structure of A 1Àx Sn 9Àx Bi 11+x Se 26 (A=K, Rb, Cs) were predicted on the basis of the homologous series A m [M 6 Se 8 ] m [M 5+n Se 9+n ] (M=Sn, Bi) and targeted for synthesis. A 1Àx Sn 9Àx Bi 11+x Se 26 adopts a new structure type that fits the structural evolution of th