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Design and synthesis of novel chiral dihydroimidazolium cyclophanes as N-heterocyclic carbene precatalysts

✍ Scribed by Lu, Ting; Gu, Liuqun; Kang, Qiang; Zhang, Yugen

Book ID: 120843852
Publisher: Elsevier Science
Year: 2012
Tongue: French
Weight: 520 KB
Volume: 53
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2012.09.116

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## Abstract Reaction of __ortho__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) and __para__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) salts with KOBu^__t__^ and [RhCl(COD)]~2~ yields __ortho__‐ and __para__‐xylyl