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Design and Synthesis of Novel C 2 -Symmetric Chiral Piperazines and an Application to Asymmetric Acylation of σ-Symmetric 1,2-Diols

✍ Scribed by Nakamura, Daisuke; Kakiuchi, Kiyomi; Koga, Kenji; Shirai, Ryuichi


Book ID
127252475
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
82 KB
Volume
8
Category
Article
ISSN
1523-7060

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Synthesis of novel C2-symmetrical chiral
✍ Miyuki Ishizaki; Osamu Hoshino 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

## Abstract Novel C~2~‐symmetrical chiral sulfides were synthesized from (__R,R__)‐tartaric acid and their utility in the asymmetric epoxidation of aldehydes with benzyl bromide was examined. Among the sulfides used, silyl ether‐type sulfides were found to be superior to diol‐ and benzyl ether‐type