✦ LIBER ✦
Design and synthesis of AB3-type (A = 1,3,5-benzenetricarbonyl unit; B = Glu diOME or Glu7 octa OMe) peptide dendrimers: Crystal structure of the first generation
✍ Scribed by Darshan Ranganathan; Sunita Kurur; Richard Gilardi; Isabella L. Karle
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2000
- Tongue
- English
- Weight
- 227 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0006-3525
No coin nor oath required. For personal study only.
✦ Synopsis
The first generation molecule of glutamic acid-based dendrons on a 1,3,5-benzenetricarbonyl core leads to a cylindrical assembly as demonstrated by single crystal x-ray diffraction. The benzenestack (A) is stabilized by vertical NH . . . OAC hydrogen bonding with each subunit participating in three intermolecular hydrogen bonds related by three-fold rotation symmetry.