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Design and Magnetic Properties of a Magnetically Isolated GdIIICuII Pair. Crystal Structures of [Gd(hfa)3Cu(salen)], [Y(hfa)3Cu(salen)], [Gd(hfa)3Cu(salen)(Meim)], and [La(hfa)3(H2O)Cu(salen)] [hfa = Hexafluoroacetylacetonato, salen = N,N‘-Ethylenebis(salicylideneaminato), Meim = 1-Methylimidazole]

✍ Scribed by Ramade, Isabelle; Kahn, Olivier; Jeannin, Yves; Robert, Francis

Book ID
111886536
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
332 KB
Volume
36
Category
Article
ISSN
0020-1669

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Magnetically Isolated Cu II Gd III Pairs
Magnetically Isolated Cu II Gd III Pairs in the Series [Cu(acacen)Gd(pta) 3 ], [Cu(acacen)Gd(hfa) 3 ], [Cu(salen)Gd(pta) 3 ], and [Cu(salen)Gd(hfa) 3 ], [acacen = N,N ‘ -Ethylenebis(acetylacetoniminate(−)), salen = N,N ‘ -Ethylenebis(salicylideniminate(−)), hfa = 1,1,1,5,5,5-Hexafluoropentane-2,4-dionate(−), pta = 1,1,1-Trifluoro-5,5-dimethylhexane-2,4-dionate(−)]
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