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Design and Development of Functionalized Water-Soluble Phosphines: Catalytic and Biomedical Implications

✍ Scribed by Katti, Kattesh V.; Gali, Hariprasad; Smith, Charles J.; Berning, Douglas E.


Book ID
115479419
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
126 KB
Volume
32
Category
Article
ISSN
0001-4842

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Two new water-soluble chelating alkyl phosphines are described. The compounds are prepared by radical addition of allylic substrates to 1,2-bis(phosphino)ethane in methanol. Complexes with the stoichiometry of 1.5: 1 diphosphine:rhodium(I) are effective in the hydrogenation of the olefins I-hexene a