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Description of ternary liquid-liquid equilibria near the critical region by scaling law

✍ Scribed by Chongli Zhong; Wenchuan Wang; Aage Fredenslund


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
461 KB
Volume
83
Category
Article
ISSN
0378-3812

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Thermodynamics of liquid-liquid equilibr
✍ Juan JosΓ© De Pablo; John M. Prausnitz πŸ“‚ Article πŸ“… 1988 πŸ› American Institute of Chemical Engineers 🌐 English βš– 1021 KB

To obtain good representation in the liquid-liquid critical region, a semitheoretical correction is added to a conventional expression (e.g., van Laar or NRTL) for the excess Gibbs energy of a binary or ternary system along the coexistence curve. This correction is an exponential function of a suita