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Derivatives of Homopseudopelletierine: Completely Enolic β-Ketoesters

✍ Scribed by CHAPMAN, ORVILLE L.; MEINWALD, JERROLD


Book ID
125901293
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
438 KB
Volume
23
Category
Article
ISSN
0022-3263

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The enolates of cyclic ~-ketoesters react with electrophilic acetylenes to give the corresponding Michael adducts in good yields when the reaction is performed in acetone in the presence of catalytic amounts of K2CO 3. The Michael adducts resulting from ethynylmethylketone, when refluxed in toluene