𝔖 Bobbio Scriptorium
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Derivatives of diazirine-3,3-dicarboxylic acid

✍ Scribed by G. V. Shustov; N. B. Tavakalyan; A. P. Pleshkova; R. G. Kostyanovskii


Book ID
112348782
Publisher
Springer US
Year
1981
Tongue
English
Weight
504 KB
Volume
17
Category
Article
ISSN
0009-3122

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Exchange reactions of diazirines: 3-X-3-
✍ Robert A Moss; Michał Fedorynski; Graz̀yna Kmiecik-Ławrynowicz; Jacek Terpinski 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 237 KB

3-Bromo-3-methyldiazirine readily undergoes exchange reactions with F-, MeO-, CN-, or Ng-. New carbene precursors can thus be prepared. 3-Halo-3-aryldiazirines undergo synthetically useful exchange reactions with strong nucleophiles that proceed via tight diazlrinium halide ion pairs and provide co