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Derivatives of Coumaran. I. 2-Benzyl-5(and 6)-methoxycoumaran-3-one

✍ Scribed by Shriner, R. L.; Damschroder, R. E.

Book ID
127101114
Publisher
American Chemical Society
Year
1938
Tongue
English
Weight
310 KB
Volume
60
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

(3Z)-2-Benzyl-3-benzylΒ­idene-6-phenyl-2-
(3Z)-2-Benzyl-3-benzylΒ­idene-6-phenyl-2-azaΒ­bicycloΒ­[2.2.2]octan-5-one
✍ Sridhar, B. ;Ravikumar, K. ;Mahesh, M. ;Reddy, V. V. Narayana πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 223 KB

In the title compound, C~27~H~25~NO, all three rings in the azabicyclo[2.2.2]octane unit adopt a boat conformation. An intermolecular Cβ€”H...O interaction forms a characteristic __R__ ~2~ ^2^(14) motif dimer in the crystal packing.

The structures of five bicyclic lactams:
The structures of five bicyclic lactams: 2-benzyl-3-oxo-2-azabicyclo[2.2.1]hept-6-exo-yl p-toluenesulfonate, 2-benzyl-6-exo-phenoxy-2-azabicyclo[2.2.1]heptan-3-one, 2-benzyl-6-exo-(2-iodo-4-methylphenoxy)-2-azabicyclo[2.2.1]heptan-3-one, 2-benzyl-6-exo-(2,6-diiodo-4-methylphenoxy)-2-azabicyclo[2.2.1]heptan-3-one and 2-benzyl-6-exo-phenoxy-2-azabicyclo[2.2.2]octan-3-one
✍ Ammon, H. L. ;Mazzocchi, P. H. ;Liu, L. ;Colicelli, E. C. ;Doherty, R. ;Stewart, πŸ“‚ Article πŸ“… 1982 πŸ› International Union of Crystallography βš– 789 KB