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Derivatives of acetoacetic acid. Part VI. A synthesis of 1 : 3-oxazine derivatives employing diketen

✍ Scribed by Lacey, R. N.


Book ID
121417456
Publisher
The Royal Society of Chemistry
Year
1954
Weight
582 KB
Category
Article
ISSN
0368-1769

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Asymmetric Synthesis Employing a Chiral
✍ Oliver Achatz; Andrea Grandl; Klaus Theodor Wanner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 423 KB πŸ‘ 1 views

A new asymmetric synthesis of disubstituted Ξ±-amino acids From the major diastereomers 17c-d the corresponding Ξ±amino acids 19c-d are obtained enantiomerically pure upon is presented. This synthesis is based on the chiral 5-methoxy-1,4-oxazin-2-one derivative 5 relying on the Ξ±-hydroxy acid hydroly