Derivatives of 6-Deoxy-6-mercapto-D-fructose
β Scribed by Feather, M. S.; Whistler, Roy L.
- Book ID
- 115507684
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 421 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A chemoenzymatic route to 6-deoxy (D-fructose 5b and L-sochose 5a) is described.This method is based on conversion of racemic 2.3-dihydroxybutyraldehyde to 5a and Sb catalyzed by spinach leaves Transketolase. Only the (R,R) and (R,S) isomers of 2,3-dihydroxybutymkiehyde react, yielding 6-deoxy-D-fmc
2-BenzyI-N-tert-butoxycarbonyl-1,5-imino-1,2,5-trideoxy-D-xylitol (4) and 5-amino-4benzyl-4,5-dideoxy-L-xylose (13) were prepared in optically pure form.