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Derivation of the quantum Langevin equation

โœ Scribed by N.G. van Kampen


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
302 KB
Volume
71
Category
Article
ISSN
0167-7322

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โœฆ Synopsis


The phenomenological approach to the Langevin equation breaks down for quantum systems. It is necessary to take into account explicitly an external bath, which causes the damping and fluctuations. The question then is whether there exists an autonomous equation of motion for the system itself, with or without a memory kernel. Some simple cases are listed and for one case the derivation of Langevin's equation is carried out. It is compared to the exact result, which leads to the following conclusions. The equation is true only to the lowest order in the interaction between system and bath. In general there is a memory kernel but in two special cases the damping reduces to a simple proportionality with a friction coefficient ("Ohmic case").


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โœ G Kemeny ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 550 KB

The Langevin equation is derived for a system of interacting molecules by a double Fourier transformation of the Hamiltonian. The transformations are with respect to the molecular equilibrium positions and the deviations, respectively. The potential energy term is then the generator of mode interact