Derivation of the parameters of Brownian rotational motion from molecular spectra
β Scribed by S. A. Kirillov; I. Ya. Rivelis
- Publisher
- Springer US
- Year
- 1973
- Tongue
- English
- Weight
- 191 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0021-9037
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π SIMILAR VOLUMES
It is shown how the complete solution of the Smoluchkowski equation for rotational brownian motion may be obtained to any order in the applied field strength by means of Picard's method of successive approximatrons. The procedure is illustrated by considering the particular case where the applied el
The rotational Raman spectra of C2D,, C2HD, and CH,CD2 are presented with a resolution of ca 0.3 cm-'. A computer simulation has been carried out to reproduce the observed contours from literature values of the rotational constants. The molecular polarizability parameters are determined with ca 10%