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Derivate des borols: VII. (η5-borol)rhodium-komplexe und nucleophiler abbau von μ-(η5-1-phenylborol)-bis[(η5-1-phenylborol)rhodium]

✍ Scribed by G.E. Herberich; U. Büschges; B. Hessner; H. Lüthe


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
825 KB
Volume
312
Category
Article
ISSN
0022-328X

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Derivate des Borols, XVIII. Tricarbonyl[
✍ Herberich, Gerhard E. ;Carstensen, Tobias ;Klaff, Norbert ;Neuschütz, Mark 📂 Article 📅 1992 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 556 KB

The borole complex (C4H4BPh)Fe(C0)3 (1) undergoes Friedel-Crafts acetylation (MeCOC1/AlC13) at the meta-position of the phenyl substituent while the derivatives (C4H4BPh)Fe(C0)2L (3, a: L = NMe3, b: L = PMe3) are acetylated at the 2-position of the borole ring. Organolithium reagents (LiMe, LiBu) ad