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Deracemization of bilirubin as the marker of the chirality of micellar aggregates

โœ Scribed by Alessandro Sorrenti; Barbara Altieri; Francesca Ceccacci; Pietro Di Profio; Raimondo Germani; Luisa Giansanti; Gianfranco Savelli; Giovanna Mancini

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
617 KB
Volume
24
Category
Article
ISSN
0899-0042

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โœฆ Synopsis

Abstract

The deracemization of bilirubin in micellar aggregates of structurally correlated chiral surfactants was studied by circular dichroism experiments and exploited as the marker of the expression of chirality of the aggregates. The obtained results suggest that the hydrophobic interactions control the transfer of chirality from the monomers to the aggregates, and that different regions of the same aggregate might feature opposite enantiorecognition capabilities. Chirality, 2011. ยฉ 2011 Wiley Periodicals, Inc.

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