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Der Weg in die Zukunft: In-vivo-Pathologie durch Laserscan-Mikroskopie

✍ Scribed by G. Hüttmann; M. Löning


Publisher
Springer
Year
2007
Tongue
German
Weight
822 KB
Volume
40
Category
Article
ISSN
0017-5994

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Ein neuer Weg zuN-silylierten Diaminosul
✍ Herberhold, Max ;Frank, Stefan M. ;Wrackmeyer, Bernd ;Borrmann, Horst ;Simon, Ar 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 313 KB

Sulfur diimides (R1N)S(NR2) (R1, RZ = tBu, SiMe,; la-c) and ] react fast and quantitatively in a 1: 1 ratio to give diaminosulfanes (4, 5) by cleavage of the Si-Si bond. The solid-state structure of tBu-(SiMeC12)N -S -N(SiMe3)SiMeC12 (4b) has been studied both by X-ray crystallography and 29Si-NMR