𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Der Färbemechanismus neutralziehender Metallkomplexfarbstoffe: III. Adsorptionsisothermen auf Naturseide und Wolle. 4. Mitteilung über textilchemische Untersuchungen

✍ Scribed by G. Back; Hch. Zollinger


Publisher
John Wiley and Sons
Year
1959
Tongue
German
Weight
318 KB
Volume
42
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Adsorption isotherms of two neutral dyeing 1:2 chromium complex dyes without ionized substituents on wool, acetylated wool and silk have been determined.

In principle, the dyeing mechanism of these dyes on these fibres shows the same characteristics as on polyamides investigated in former papers:two processes, namely salt formation with basic groups of the fibre and a solution mechanism, procecd simultaneously. On wool, the solution mechanism is of minor importance.

The affinity of one of these dyes for wool via the salt binding mechanism has been calculated. It is lower than its affinity for nylon 66.


📜 SIMILAR VOLUMES


Der Färbemechanismus neutralziehender Me
✍ G. Back; Hc H. Zollinger 📂 Article 📅 1958 🏛 John Wiley and Sons 🌐 German ⚖ 673 KB

Mitteilung fiber tcxtilchemische Untersuchungen von G . Back2) und Hch. Zollinger (4. X. 58) 1. Problemstellung. Fur Farbungen von hohem Echtheitsniveau auf Proteinfasern sind in neuerer Zeit die sogenannten neutralziehenden Metallkomplexfarbstoffe entwickelt worden. Nach Vorarbeiten von verschieden

Der Färbemechanismus neutralziehender Me
✍ G. Back; Hch. Zollinger 📂 Article 📅 1959 🏛 John Wiley and Sons 🌐 German ⚖ 766 KB

## Abstract The adsorption isotherms of a neutral‐dyeing 1:2 chromium complex dyestuff on nylon 66 show that the dyeing process consists of a competitive adsorption at the amino end‐groups (salt binding mechanism, analogous to the adsorption of acid dyes and mineral acids) and a partition process (