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Deprotonation Pathway in the Reaction of Me 6 Si 2 with MeLi

✍ Scribed by Liu, Ling-Kang; Luh, Lung-Shiang

Book ID
125922833
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
85 KB
Volume
19
Category
Article
ISSN
0276-7333

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✍ Nadine GΓΆtz; Sebastian Herler; Peter Mayer; Axel Schulz; Alexander Villinger; Ja πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 187 KB

## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (