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Deprotection of S-Acetamidomethyl Cysteine-Containing Peptides by Silver Trifluoromethanesulfonate Avoids the Oxidization of Methionines

✍ Scribed by M.J. Hunter; E.A. Komives


Book ID
102968661
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
527 KB
Volume
228
Category
Article
ISSN
0003-2697

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Iodine Oxidation of S-Trityl- and S-Acet
✍ Peter Sieber; Bruno Kamber; Bernhard Riniker; Werner Rittel 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 351 KB

## Abstract Cystine peptides are conveniently prepared from __S__‐acetamidomethyl‐ or __S__‐trityl‐protected cysteine derivatives by direct oxidation with iodine. Since the reaction proceeds through the formation of sulfenyl iodides, these highly reactive groups may substitute the indole ring of tr