Polarization labelling spectroscopy is applied to study excited states of K2 lying in the energy range 23800-25800 cm-' above the bottom of the ground state. The two observed states are identified as 3 'l&(4 'S+S 'P) and 3 '&/ (4 \*S+ 3 'D). Molecular constants are derived for both states from a Dun
Depletion spectroscopy of the Sr2 B 1Πu ← X 1Σ+g system
✍ Scribed by C. Bordas; M. Broyer; J. Chevaleyre; Ph. Dugourd
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 529 KB
- Volume
- 197
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Spectroscopic studies have been performed on Srz molecules produced in a seeded molecular beam. Two-photon excitation techniques were used to investigate excited states of Sr2: the A+X system has been observed using two-photon ionization while depletion spectroscopy allowed us to characterize a new state of Sr2, B 'II., dissociating in (5s') 'S + (5sSp)'P. Preliminary spectroscopic constants are deduced and the dissociation mechanism allowing depletion is discussed.
📜 SIMILAR VOLUMES
## spectra of 3gic2. 3qK4'kC and 4t The ass$nment of B 'n,-X K;z formed in 3 nozzle beam Iuve been measured and analyscd. t E,'has been revised. Correct vibrational rend rotations1 constm-m for both the ground S i rz and the excited B \*R, states are-reported. =
Cross scct~ons fix vrbrntional c-xltntlon (VE) of the X 1 Z: state of LQ wa formation of the cxnted A '$ or B II-I" eiectromc states are reported. For VE through the A ' ~6 state. the cross secttons are nearly constant for forming X ' ?I; (3 < U" < 9) WI electron colhslonnl cwltatlon. For photon pum