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Dependence of the stereochemistries of intramolecular [8+2] cycloadditions of alkenylheptafulvenes on tetraenophile stereochemistry

โœ Scribed by Ching-Yang Liu; K.N. Houk

Book ID
104227489
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
214 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœ D Becker; N Haddad ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

The stereoselectivity in [2+2] photocycloaddition was studied on System I. Compounds 2, m, and 15a cyclize in high yield and the selectivity is higher than 94%.