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Dependence of the Regioselectivity of Photo-oxidative Ring Opening of the Chlorophyll Macrocycle on the Complexed Metal Ion

✍ Scribed by José Iturraspe; Albert Gossauer

Publisher
John Wiley and Sons
Year
1991
Tongue
German
Weight
300 KB
Volume
74
Category
Article
ISSN
0018-019X

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✦ Synopsis

We thank Prof. Ph. Mutile for the communication of his results prior to publication.

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✍ Philipp Schultz-Grunow; Thomas A. Kaden 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 254 KB 👁 1 views

## Abstract The complexation kinetics of the two macrocycles **1** and **2** with Co^2+^, Ni^2+^, Cu^2+^ and Zn^2+^ have been measured by pH‐stat techniques. The rates are first order in metal and ligand concentration and depend upon the pH. This results from the different reactivities of the vario