✦ LIBER ✦

Dependence of the primary isotope effect (kH/kD) on base strength for the primary amine catalyzed ionization of nitroethane

✍ Scribed by Dixon, J. Edward.; Bruice, Thomas C.

Book ID: 126188539
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 677 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00707a028

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Effects of mixed H2OCH3CN solvents on th

Effects of mixed H2OCH3CN solvents on the Brønsted coefficient for the intramolecular general base-catalyzed cleavage of ionized phenyl salicylate in the presence of primary and secondary amines

✍ M. Niyaz Khan; Z. Arifin; A. George; I. A. Wahab 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 148 KB 👁 1 views

Nucleophilic second-order rate constants, k n ms , for the reactions of several primary and secondary amines with ionized phenyl salicylate (PS Ϫ ) show a nonlinear decrease with the increase in the content of CH 3 CN from 2 to Յ50% v/v in mixed aqueous solvent. The values of k n ms remain almost un

Additions and Corrections - The Primary

Additions and Corrections - The Primary Carbon Isotope Effect on the Ionization of Triphenylmethyl Chloride. Experimental Determination, Theoretical Justification, and Implications for Carbon Isotope Effects on Nucleophilic Substitution at Saturated Carbon.

✍ Kresge, A.; Lichtin, N.; Rao, K.; Weston, Jr., R. 📂 Article 📅 1965 🏛 American Chemical Society 🌐 English ⚖ 216 KB