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Dependence of the Glass Transition Temperature of Polymer Films on Interfacial Energy and Thickness

✍ Scribed by Fryer, David S.; Peters, Richard D.; Kim, Eui Jun; Tomaszewski, Jeanne E.; de Pablo, Juan J.; Nealey, Paul F.; White, Chris C.; Wu, Wen-li


Book ID
119955326
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
116 KB
Volume
34
Category
Article
ISSN
0024-9297

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## Abstract We present results of molecular dynamics simulations for free‐standing and supported thin films of a nonentangled polymer melt using a coarse‐grained (bead‐spring) model. Our discussion is mainly concerned with the equilibrium properties of the films above the critical temperature (__T_