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Dependence of geminal1H−1H and31P−1H spin-spin coupling constants on the specific intramolecular C−H...X interaction

✍ Scribed by A. V. Afonin; D. E. Perez; M. C. Ruiz de Azua; R. H. Contreras; P. Lazzeretti

Publisher
Springer
Year
1997
Tongue
English
Weight
308 KB
Volume
46
Category
Article
ISSN
1573-9171

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Trivinylphosphine and trivinylphosphine
Trivinylphosphine and trivinylphosphine chalcogenides: stereochemical trends of 31P1H spin–spin coupling constants
✍ Sergey V. Fedorov; Leonid B. Krivdin; Yury Yu. Rusakov; Nataliya A. Chernysheva; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

A combined theoretical and experimental study of the stereochemical behavior of (31)P-(1)H spin-spin coupling constants has been performed in the series of trivinylphosphine and related trivinylphosphine oxide, sulfide and selenide. Theoretical energy-based conformational analysis of the title compo