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Dependence of 13C Chemical Shifts on Glycosidic Torsional Angles in Ribonucleic Acids

✍ Scribed by Ghose, Ranajeet; Marino, John P.; Wiberg, K. B.; Prestegard, James H.


Book ID
126102210
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
298 KB
Volume
116
Category
Article
ISSN
0002-7863

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The effect of the glycosidic torsion angle on ~3C and ~SN shifts of the sugar and base moieties of guanosine nucleotides was investigated by comparing the sites in two model G-tetrad oligodeoxynucleotides that contain guanosine residues alternately with syn and anti bases. The sugar puckering has be