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Deoxygenative Cycloaddition of Aldehydes with Alkynes Mediated by AlCl3 and Zirconium: Formation of Cyclopentadiene Derivatives

✍ Scribed by Zhenfeng Xi; Pixu Li

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 75 KB
Volume: 39
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20000818)39:16<2950::aid-anie2950>3.0.co;2-y

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The development of methodologies for carbon À carbon bond formation by deoxygenation of the CO moieties in carbonyl compounds has attracted much attention as a powerful synthetic strategy. [1] In general, two types of CÀC bond-forming reactions that involve the deoxygenation of CÀO double bonds in c