๐”– Bobbio Scriptorium
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Deoxygenation of aldehydes and ketones; a new general reaction of dibromocarbene and dibromocarbonyl ylides

โœ Scribed by Zhenwei Huan; John A. Landgrebe; Kimberly Peterson

Book ID
104221387
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
173 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The treatment of a variety of aldehydes and ketones with phenyl(tribromomethyl)mercury results in the production of carbon monoxide from the deoxygenation of the carbonyl group by dibromocarbene.

Until now, reports of the production of carbon monoxide from the reaction

๐Ÿ“œ SIMILAR VOLUMES

A new alkenylation reaction of aldehydes
A new alkenylation reaction of aldehydes and ketones using vinylalanes
โœ Howard Newman ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

I would like to report that vinylalanes react smoothly, conveniently and rapidly with aldehydes and ketones in ether-hydrocarbon or hydrocarbon solvents at room temperature to give the corresponding allylic alcohols. The reaction proceeds stereospecifically to give the trans ally1 alcohol as indicat