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Deoxy-nitrosugars 12th communication Synthesis of isosteric mono-phosphonate analogues of β-and α-D-fructose 2,6-bisphosphate

✍ Scribed by Roger Meuwly; Andrea Vasella

Publisher: John Wiley and Sons
Year: 1986
Tongue: German
Weight: 703 KB
Volume: 69
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19860690402

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✦ Synopsis

The 8-o-configuration of 1 was deduced from its I3C-NMR spectrum [2].

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Deoxy-nitrosugars. 10th Communication. S

Deoxy-nitrosugars. 10th Communication. Synthesis of Isosteric Phosphonate Analogues of Ulose-1-Phosphates

✍ Radomir Julina; Andrea Vasella 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 898 KB

## Abstract A general approach to isosteric phosphonate analogues of ulose‐l‐phosphates is described. A base‐catalysed chain elongation __via__ a __Michael__ addition of 1‐deoxy‐1‐nitro‐sugars **4, 8**, and **16** to the vinylphosphonate **18** followed by hydrolysis of the nitro adducts gave the a