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Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: From κ3- to Ionic “κ0”-Tp′

✍ Scribed by Margarita Paneque; Sabine Sirol; Marianela Trujillo; Enrique Gutiérrez-Puebla; M. Angeles Monge; Ernesto Carmona


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
126 KB
Volume
39
Category
Article
ISSN
0044-8249

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Denticity Changes of Hydrotris(pyrazolyl
✍ Margarita Paneque; Sabine Sirol; Marianela Trujillo; Enrique Gutiérrez-Puebla; M 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 1 views

The formally tridentate cyclopentadienyl and hydrotris-(pyrazolyl)borate ligands are important auxiliary ligands in organometallic chemistry. [1, 2] Most often they act as spectators, and chemical transformation occurs at the metal center or at other coordinated ligands. However, in some instances t