In this work the measurements of eleclrical conductivity, viscosity and density of NaI salt in formamide solutions in the composition range %21 mole "4 and in the temperature range 35-8O'C are reported. The experimental data have been analyzed with equations utilized for transport in glassforming li
Density, viscosity and electrical conductivity of LiCl and some uni-bivalent electrolytes in formamide solutions at 25°C
✍ Scribed by P. Bruno; M. Della Monica
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 669 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
ZnCI,. ZnBrZ and Znl, salts. The linear dependence of the density of the investigated salts on the concentration IS interpreted assuming that the structural configuratlon of the solvent formamide remains unchanged in the concentration range experienced. Viscosity and conductivity data have been treated following a proposal of Angell. A least-squares program used to linearise the Ign and the Ig,l functions against l/(No -N) gives N n values. the glass-transition concentration at 25°C. acceptably low and sufficiently close in most casts.
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The Robinson-Stokes equation has been tested for conductance measurements on some u&-univalent electrolytes in formamide at 25°C and it has been observed that the equation IS applicable up to a concentration of 175.0 x 10m4 mole/litre. A method, based on this equation, for the determination of ion-s
Equivalent conductances of [Cu(en),]X, and [Ni(en)s]XI (X = Cl, Br and I) solutions in both water and dioxane-water mixtures at 25°C were measured in different compositions covering the range 0.00-53.00 wt. "/.. The data were anal@ using the Fuoss-Edelson method to obtain the limiting equivalent con
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