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Density Functional Theory and X-ray Analysis of the Structural Variability in η 5 ,η 5 ,η 1 -Tris(ring) Rare Earth/Actinide Tetramethylpyrrolyl Complexes, (C 5 Me 5 ) 2 M(NC 4 Me 4 )

✍ Scribed by Webster, Christopher L.; Bates, Jefferson E.; Fang, Ming; Ziller, Joseph W.; Furche, Filipp; Evans, William J.

Book ID
126836289
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
736 KB
Volume
52
Category
Article
ISSN
0020-1669

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3