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Density Functional Theory and Low-Temperature Matrix Investigations of CO-Loss Photochemistry from [(C5R5)Ru(CO)2]2(R = H, Me) Complexes

✍ Scribed by Sibrina N. Collins; Constance M. Brett; Bruce E. Bursten


Book ID
106406209
Publisher
Springer
Year
2004
Tongue
English
Weight
401 KB
Volume
15
Category
Article
ISSN
1040-7278

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Photochemical reactions of [(Ξ·5-C5R5)Mn(
✍ Bentley J. Palmer; Anna Becalska; Ross H. Hill πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 646 KB

## The photolysis of [(T'-CsR,)Mn(CO),(NO)]' (RS=HZ, H4Me, MeS) was studied by Fourier transform IR spectroscopy in a low temperature 1,2-epoxyethylbenzene glass and in surface films. In each case the primary photoproduct was found to be [(~5-CsRS)Mn(CO)(NO)]'. The result of subsequent photoIysis