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Density Functional Study of N- Heterocyclic and Diamino Carbene Complexes: Comparison with Phosphines

✍ Scribed by Lee, Ming-Tsung; Hu, Ching-Han

Book ID
120279360
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
101 KB
Volume
23
Category
Article
ISSN
0276-7333

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N-Heterocyclic Carbene Functionalized Iridium Phosphinidene Complex [Cp*(NHC)IrPMes*]: Comparison of Phosphinidene, Imido, and Carbene Complexes
✍ Arjan T. Termaten; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Sp πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 153 KB πŸ‘ 1 views

## Abstract The novel phosphinidene complex [Cp\*(NHC)Irο£ΎPMes\*] (**3**; NHC=1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene) was prepared in high yield from [Cp\*(NHC)IrCl~2~] (**2**) and [LiPHMes\*]**β‹…**3 THF. It represents the first example of an NHC ligated transition metal phosphinidene complex