Density functional computational thermochemistry: determination of the enthalpy of formation of sulfine, CH2SO, at room temperature
✍ Scribed by Oscar N. Ventura; Martina Kieninger; Raúl E. Cachau; Sandor Suhai
- Book ID
- 108312059
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 116 KB
- Volume
- 329
- Category
- Article
- ISSN
- 0009-2614
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A synthesis of high-purity silicon disulfide SiS2 is described, and the F.t.-Raman spectrum of the solid is reported for the first time. The standard massic energy of reaction of SiS2(cr) with fluorine was measured in a bomb calorimeter. The combustion reaction was shown to proceed as follows: SiS2(
new DfH°m (GeS,cr,298.15 K) obtained in Part II of this study (J. Chem. Thermodynamics 1994, 26, 727), yield several derived results for DfH°m(GeS2,cr,298.15 K) that are in reasonable agreement with the calorimetric determinations. The standard molar enthalpy of the transition: GeS2(vit) = GeS2(cr):