The principle of hard and soft acids and bases is applied in the local sense to rationalize the regiochemistry in the cycloaddition reactions of a few typical 1,3-dipoles, in particular those with phosphorus-containing dipolarophiles. Local softnesses are calculated using density functional theory.
Density Functional Approach to Regiochemistry, Activation Energy, and Hardness Profile in 1,3-Dipolar Cycloadditions
✍ Scribed by Chandra, Asit K.; Nguyen, Minh Tho
- Book ID
- 120287879
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 108 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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