Density Functional and ab Initio Investigation of CF 2 ICF 2 I and CF 2 CF 2 I Radicals in Gas and Solution Phases
โ Scribed by Kim, Joonghan; Jun, Sunhong; Kim, Jeongho; Ihee, Hyotcherl
- Book ID
- 124063479
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 177 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori
The following reactions: (1, -1) . CF, + CzFSC1 CF&l + ' CzF5 (2) (3) were studied over the temperature ranges 533-687 K, 563-663 K, and 503-613 K for the forward reactions respectively and over 683-763 K, for the back reaction. Arrhenius parameters for chlorine atom transfer were determined re